„Diastereoselective Hydride Transfer Enables a Synthesis of Chiral 1,5-Carboxamido-Trifluoromethylcarbinols“

Roberto Tinelli, Manuel Schupp, Immo Klose, Saad Shaaban, Boris Maryasin, Nuno Maulide*

Chem. Sci. 2024, 15, 15751-15756; doi:10.1039/D4SC05049E

„Low-Temperature Activation of Fluorspar in Water via BrØnsted and Lewis Acid Cooperativity“

Immo Klose§ (equal contribution), Calum Patel,§ Anirban Mondal,§ Andrew Schwarz, Gabriele Pupo, Véronique Gouverneur*

Nature 2024, 635, 359–364; doi:10.1038/s41586-024-08125-1

„Hydride Shuttle Catalysis: From Conventional to Inverse Mode“

Iakovos Saridakis,§ Immo Klose§ (equal contribution), Benjamin Jones,§ Nuno Maulide*

JACS Au 2024, 4, 9, 3358–3369; doi:10.1021/jacsau.4c00532

„Stereodivergent Synthesis of 1,4-Dicarbonyl Compounds through Sulfonium Rearrangement: Mechanistic Investigation, Stereocontrolled Access to γ-Lactones and γ-Lactams, and Total Synthesis of Paraconic Acids“

Nicolas G.-Simonian, Philipp Spieß, Margaux Riomet, Boris Maryasin, Immo Klose, Alexander Beaton Garcia, Laurin Pollesböck, Dainis Kaldre, Uroš Todorovic, Julia Minghua Liu, Daniel Kaiser, Leticia González, Nuno Maulide*

J. Am. Chem. Soc. 2024, 146, 13914-13923; doi: 10.1021/jacs.4c01755

„Sulfonium Rearrangements Enable the Direct Preparation of Sulfenyl Imidinium Salts“

Carlos R. Gonçalves§, Immo Klose§ (equal contribution), Simone Placidi, Daniel Kaiser, and Nuno Maulide*

Angew. Chem. Int. Ed. 2024, e202316579; doi: 10.1002/ange.202316579

„Inverse hydride shuttle catalysis enables the stereoselective one-step synthesis of complex frameworks“

Immo Klose, Giovanni Di Mauro, Dainis Kaldre and Nuno Maulide

Nature Chem. 2022, 14, 1306–1310; doi: 10.1038/s41557-022-00991-4

„As Similar As Possible, As Different As Necessary — On-Site Laboratory Teaching during the COVID-19 Pandemic“

Ivan Mosiagin§, Katharina Pallitsch§, Immo Klose, Alexander Preinfalk, Nuno Maulide.

J. Chem. Educ. 2021, 98, 3143–3152; doi:10.1021/acs.jchemed.1c00615

"Straightforward Access to Thiocyanates via Dealkylative Cyanation of Sulfoxides“

Uroš Todorović, Immo Klose§ (equal contribution), Nuno Maulide.

Org. Lett. 2021, 23, 2510–2513; doi: 10.1021/acs.orglett.1c00460

Amongst the 10 Most Read Articles in Organic Letters March 2021.

"Facile C–S Bond Cleavage of Aryl Sulfoxides Promoted by Brønsted Acid“

Bogdan R. Brutiu, Immo Klose, Nuno Maulide.

Synlett 2021, 32, 488-490; doi: 10.1055/s-0040-1707109

"Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts“

Daniel Kaiser, Immo Klose, Rik Oost, James Neuhaus, Nuno Maulide.

Chem. Rev. 2019, 119, 8701-8780; doi: 10.1021/acs.chemrev.9b00111

Voted amongst the Top 10 Reviews in the “Your Favorite Review“-campaign of 2019.

„Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement“

Dainis Kaldre§, Immo Klose§ (equal contribution), Nuno Maulide.

Science 2018, 361, 664-667; doi: 10.1126/science.aat5883

Selected as "SYNFACTS of the month": Synfacts 2018, 14, 1189.

Highlighted in Org. Process Res. Dev. 2018, 22, 1335.

"Unusual Mechanisms in Claisen Rearrangements: an Ionic Fragmentation leading to a meta-Selective Rearrangement“

Boris Maryasin, Dainis Kaldre, Renan Galaverna, Immo Klose, Stefan Ruider, Martina Drescher, Hanspeter Kählig, Leticia González, Marcos Eberlin, Igor Jurberg, Nuno Maulide.

Chem. Sci. 2018, 9, 4124-4131; doi: 10.1039/c7sc04736c

„Synthesis and Photocatalytic Reactivity of Vinylsulfonium Ylides“

Immo Klose, Antonio Misale, Nuno Maulide.

J. Org. Chem. 2016, 81, 7201-7210; doi: 10.1021/acs.joc.6b01073

„Loganin and secologanin derived tryptamine–iridoid alkaloids from Palicourea crocea and Palicourea padifolia (Rubiaceae)“

Andreas Berger, Maria Katharina Kostyan, Immo Klose, Michael Gastegger, Eberhard Lorbeer, Lothar Brecker, Johann Schinnerl.

Phytochemistry 2015, 116, 162; doi: 10.1016/j.phytochem.2015.05.013